2019

C. Schwarz, J. Handelmann, D. M. Baier, A. Ouissa,V. H. Gessner*
Mono- and diylide-substituted phosphines (YPhos): impact of the ligand properties on the catalytic activity in gold(I)-catalysed hydroaminations
Catal. Sci. Technol. 2019, 6808-6815, DOI: 10.1039/C9CY01861A

X.-Q. Hu, D. Lichte, I. Rodstein, P. Weber, A.-K. Seitz, T. Scherpf, V. H. Gessner*, L. J. Gooßen*
Ylide-Functionalized Phosphine (YPhos)–Palladium Catalysts: Selective Monoarylation of Alkyl Ketones with Aryl Chlorides
Org. Lett. 2019, 21, 18, 7558-7562. DOI: 10.1021/acs.orglett.9b02830


L.T. Scharf, A. Kowsari, T. Scherpf, K.-S. Feichtner, V.H. Gessner*
Cooperative Bond Activation Reactions with Nickel and Palladium Carbene Complexes with a PC_carbene_S Pincer Ligand
Organometallics 2019, 38, 21, 4093-4104. DOI: 10.1021/acs.organomet.9b00386


V. H. Gessner
Palladium Catalyzed Amination of Aryl Chlorides
GIT Laboratory Journal - Business Web for Users in Science and Industrie, Jul. 09, 2019. link


L. T. Scharf  K.‐S. Feichtner  V. H. Gessner*
Carbon Dioxide Catalyzed Cyclometallation of a Carbene Complex: Synthesis and Mechanism
Eur. J. Inorg. Chem. 2019, 25, 2990. DOI: 10.1002/ejic.201900299

T. Scherpf, I. Rodstein, M. Paassen, V. H. Gessner*
Group 9 and 10 Metal Complexes of an Ylide-Substituted Phosphine: Coordination versus Cyclometalation and Oxidative Addition
Inorganic Chemistry 2019, 58(12), 8151-8161. DOI: 10.1021/acs.inorgchem.9b00948

C. Schwarz, T. Scherpf, I. Rodstein, J. Weismann, K.‐S. Feichtner, V. H. Gessner*
Ylide‐Functionalization via Metalated Ylides: Synthesis and Structural Properties
ChemistryOPEN 2019, 8(5), 621. DOI: 10.1002/open.201900094


C. Mohapatra, L. Scharf, T. Scherpf, B. Mallick, K.-S. Feichtner, C. Schwarz, V. H. Gessner*
Isolation of a Diylide-Stabilized Stannylene and Germylene: Enhanced Donor Strength through Coplanar Lone Pair Alignment
Angew. Chem. Int. Ed. 2019, 58, 22, 7459-7463. DOI: 10.1002/anie.201902831

C. Schwarz,  L. T. Scharf, T. Scherpf, J. Weismann, V. H. Gessner*
Isolation of the Metalated Ylides [Ph3P−C−CN]M (M=Li, Na, K): Influence of the Metal Ion on the Structure and Bonding Situation
Chem. Eur. J. 2019, 25,11, 2793-2802. DOI: 10.1002/chem.201805421.

P. Weber, T. Scherpf, I. Rodstein, D. Lichte, L. T. Scharf, L. J. Gooßen*, V. H. Gessner*
A Highly Active Ylide-Functionalized Phosphine for Palladium-Catalyzed Aminations of Aryl Chlorides Ylide-functionalized phosphines: Strong Donor Ligands for Homogenous Catalysis
Angew. Chem. Int. Ed. 2019, 58, 3203-3207. DOI: 10.1002/anie.201810696